Seminar Abstract
February 28, 2005:
"Pattern Formation within Partially Miscible Fluid Mixtures"
Dr. Christopher Pooley
Dept. of Chemical Engineering
University of Pittsburgh
Pattern formation through phase separation is a topic of continuous
interest to both theorists and experimentalists. For example, the complex
morphologies formed by binary, immiscible mixtures are still a topic of
extensive study. In this talk, results from two novel systems will be
presented. First, using a thermal lattice Boltzmann model, we examine the
rich phase behavior that develops when partially miscible fluids evolve in
the presence of a vertical temperature gradient, which encompasses the
critical temperature of the mixture. Second, we consider a system that
couples the growth of a liquid droplet with the phase separation of its
partially miscible components. To carry out this study, we first
characterize the thermodynamic properties of the system and use this
information to model the hydrodynamic behavior of the evolving
mixture. Through numerical simulations, we observe intriguing
tentacle-like structures within the nucleation and growth region. We
derive scaling arguments to characterize the growth of these structures in
both the diffusion and viscosity limited growth regimes.
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