Seminar Abstract
October 1, 2003:
"Shear-Induced Microstructure of
Near-Critical Colloid-Polymer Mixtures"
Dr. Hao Wang
Department of Physics
North Dakota State University
The microstructural response of a colloidal dispersion, near
a gas-liquid critical point, to a stationary shear flow is explored.
Starting from the N-particle Smoluchowski equation, we derive an
explicit expression for the shear rate dependence of the static
structure factor. This new expression improves our previous
treatment by taking the shear-induced distortion of the
short-ranged pair-correlation function into account, which may
become important on approach to the critical point. We also
perform small angle light scattering experiments on a
polymer-colloid mixture under stationary shear flow. Our theory
successfully explains the experimental data, especially the
collapse of the static structure factor on the gradient-vorticity
plane.
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